SECTION 1: Identification of the substance/mixture and of the company/undertaking
- Product Identifier
Product form: Mixture
Trade Name: Semco Teak Products
Product Code: Not Applicable
Product Group: Trade product
- Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses
Intended for use by the general public
Main use category: Professional use, Consumer use
Use of the substance/mixture: Water repellent wood preservative and sealer
- Uses advised against
Not to be used on work surfaces where food will be prepared
- Details of the supplier of the safety data sheet
Semco Teak Products
Serra Engineering and Manufacturing Co. Inc
PO Box 323
Phoenix, Maryland 21131 USA
T: 410-771-4025 (outside USA)
- Emergency Telephone Number
T+1-800-622-00223
Section 2 Hazard Identification
2.1 Classification of the substance or mixture
Flammable liquids, Category 3 H226
Specific target organ toxicity — Single H336
exposure, Category 3, Narcosis
Acute toxicity, category 4 H302
H312
H332
Specific organ toxicity-due to repeated exposure, H372
Category 1
Aspiration hazard, Category 1 H304
Adverse physicochemical, human health and environmental effects
Flammable liquid and vapour. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways.
2.2 Label Elements
Hazard pictograms (CLP):
Signal word (CLP): Danger
Hazardous ingredients: Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics and aromatics, Solvent Naphtha, Petroleum Distillates, Dimethyl benzene, Neodecanoic acid, 1,2,4 Trimethyl benzene
Hazard statements (CLP) : H226 - Flammable liquid and vapour
H304 - May be fatal if swallowed and enters airways
H302 - Harmful if swallowed
H312 – Harmful in contact with skin
H332 – Harmful if inhaled
H372- causes damage to organs through prolonged or regular exposure
H336 - May cause drowsiness or dizziness
Precautionary statements (CLP) : P101 - If medical advice is needed, have product container or label at hand
P102 - Keep out of reach of children
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P271 - Use only outdoors or in a well-ventilated area
P301+P310+P331 - IF SWALLOWED: Immediately call a POISON CENTER or seek medical attention. Do NOT induce vomiting
P312 - Call a doctor if you feel unwell
P403+P233 - Store in a well-ventilated place. Keep container tightly closed
P405 - Store locked up
P501 - Dispose of contents/container to a hazardous or special waste collection point
EUH-statements : EUH066 - Repeated exposure may cause skin dryness or cracking
Security closing plug for children : Applicable
Tactile warning : Applicable
2.3 Other Hazards
No additional information available
Section 3 Composition/information on ingredients
3.1 Substance
Not applicable
3.2 Mixture
Name | Product identifier | % | Classification according to Regulation (EC) | ||||||||||||||||||||||||
Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics and aromatics | (CAS No) 8052-41-3 (EINECS/ELINCS) 232-489-3 | 70-80 |
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Petroleum Distillates | (CAS No) 64742-95-6 (EINECS/ELINCS) 265-199-0 | 5-10 |
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Solvent Naphtha | (CAS No) 64741-65-7 (EINECS/ELINCS) 265-076-2 | 5-10 |
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Dimethyl benzene | (CAS No) 1330-20-7 (EINECS/ELINCS) 215-535-7 | 0.5-1.5 |
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Neodecanoic acid | (CAS No) 27253-31-2 (EINECS/ELINCS) 248-373-0 | 0.5-1.5 |
| ||||||||||||||||||||||||
1,2,4 Trimethyl benzene | (CAS No) 95-63-6 (EINECS/ELINCS) 202-436-9 | 0.25-1.25 |
|
Section 4 First Aid Measures
4.1 Description of first aid measures
If Inhaled: move person to fresh air and allow them to rest. If not breathing, give artificial respiration
In case of skin contact: Remove contaminated clothing. Wash off with soap and plenty of water. If irritation persists see medical attention
In case of eye contact: Flush eyes with water for 20 minutes, seek medical attention
If ingested: drink large quantity of water. Do NOT induce vomiting. Seek medical attention. Never give anything by mouth to an unconscious person
4.2 Most important symptoms and effects, both acute and delayed
Symptoms/injuries: May cause drowsiness, dizziness, headaches or nausea
Symptoms/injuries after skin contact: Repeated exposure may cause dry skin or cracking
Symptoms/injuries after ingestion: Risk of chemical pneumonitis
4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically
Section 5 Firefighting measures
5.1 Extinguisher media
Suitable extinguisher media: Foam, Dry Powder, Carbon dioxide or Sand
5.2 Special Hazards arising from the substance or mixture
Fire Hazard Flammable liquid and vapour
Hazardous decomposition products in case Toxic fumes may be released
of fire
5.3 Advice for firefighters
Firefighting instructions Use water spray or fog for cooling any exposed containers. Exercise caution when fighting any chemical fire.
Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus.
5.4 Further information
Containers may explode if exposed to extreme heat. Eliminate the source of ignition
Section 6 Accidental Release measures
6.1 Personal precautions, protective equipment and emergency procedures
Non-Emergency responders
Protective equipment: See Headings 7 and 8.
Emergency procedures: Evacuate unnecessary personnel. No open flames, no sparks, and no smoking.
Emergency responders
Protective equipment: Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection".
Emergency procedures: Ventilate area.
6.2 Environmental Precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up: Soak up spills with inert solids, such as sand or earth as soon as possible. Collect spillage. Store away from other materials. Notify authorities if product enters sewers or public waters.
Other information: Dispose of materials or solid residues at an authorised site or with an authorised waste collection company
6.4 Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
Section 7 Handling and Storage
7.1 Precautions for safe handling
Additional hazards when processed: Do not use in a confined space until fresh air flow established/confirm that atmosphere is not flammable or oxygen deficient. Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only non-sparking tools. Flammable vapours may accumulate in the container. Use only outdoors or in a well-ventilated area. Avoid breathing fume/gas/mist/vapours/spray.
Hygiene measures: Do not eat, drink or smoke when using this product. Always wash hands after handling the product.
7.2 Conditions for safe storage, including and incompatibilities
Storage conditions: Keep only in the original container in a cool, well ventilated place away from; Heat sources, Direct sunlight. Keep container closed when not in use.
Incompatible products: Oxidizing agents and Strong caustics (Acids/bases)
Incompatible material: Sources of ignition. Direct sunlight.
Storage area: Keep away from open flames, hot surfaces and sources of ignition. Store in a well-ventilated place.
7.3 Specific end use(s)
Showering and changing clothing is advised after using the product.
Section 8 Exposure Controls/personal Protection
8.1 Control Parameters
Component | Value form of exposure | Control parameters | Basis |
Dimethyl Benzene | TWA | 50ppm 220mg/m3 | EH40 WEL |
STEL | 100ppm 441mg/m3 | EH40 WEL | |
TWA | 50ppm 221mg/m3 | ECD 2000/39/EC | |
STEL | 100ppm 442mg/m3 | ECD 2000/39/EC |
Component | Value form of exposure | Control parameters | Basis |
1,2,4 trimethyl benzene | TWA | 20ppm 100mg/m3 | ECD 2000/39/EC |
TWA | 25ppm 125mg/m3 | EH40 WEL |
8.2 Exposure Controls
Appropriate engineering controls:
Ensure good ventilation of the work station.
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
In case of repeated or prolonged contact wear gloves
Eye protection:
Chemical goggles or safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Environmental exposure controls:
Avoid release to the environment.
Other information:
Do not eat, drink or smoke during use.
Section 9 Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Physical state Liquid
Appearance Translucent
Colour Various
Odour Solvent
Odour Threshold No Data Available
pH No Data Available
Melting point No Data Available
Boiling point 154oC
Flash Point 65 oC
Evaporation rate 0.15
Flammability No Data Available
Vapour Pressure 2mmHg
Vapour density 5.0 (air=1)
Relative density <1
Water solubility Negligible
Auto ignition temperature No Data Available
VOC content 690g/L
Explosive properties No Data Available
Oxidising properties No Data Available
9.2 Other information
No Data Available
Section 10 Stability and reactivity
10.1 Reactivity
Not established.
10.2 Chemical stability
Stable
10.3 Possibility of hazardous reactions
Not established.
10.4 Conditions to avoid
Avoid contact with hot surfaces. No flames, no sparks. Eliminate all sources of ignition.
10.5 Incompatible materials
Oxidizing agent and strong caustics (acids/bases)
10.6 Hazardous decomposition products
Carbon monoxide and carbon dioxide
Section 11 Toxicological information
11.1 Information on toxicological effects
Acute toxicity: Not classified
Skin corrosion/irritation: Not classified
Serious eye damage/irritation: Not classified
Respiratory or skin sensitivity: Not classified
Germ cell mutagenicity: Not classified
Carcinogenicity: Not classified
Reproductive toxicity: Not classified
Specific target organ toxicity (single exposure): May cause drowsiness, dizziness and headaches
Specific target organ toxicity (repeated exposure): Not classified
Aspiration Hazard: Maybe fatal if swallowed and enters airways
Potential adverse human health effects and symptoms: Based on available data, the classification criteria are not met
Section 12 Ecological information
12.1 Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment.
Hydrocarbons | Cat | LD50 | Inhalation | 1700ppm |
Dog | LD50 | Inhalation | 8000mg/m3 | |
Rabbit | LD50 | Skin | 3000mg/kg | |
Rat | LD50 | Inhalation | 5500mg/m3 | |
Rat | LD50 | Oral | 5000mg/kg | |
Petroleum Distillates | Quail | LD50 | Oral | 2150mg/kg |
Rat | LD50 | Oral | 8400mg/kg |
12.2 Persistence and degradability
Not established.
12.3 Bioaccumulative potential
Not established.
12.4 Mobility in soil
Not established.
12.5 Results of PBT and vPvB assessment
Not established.
12.6 Other adverse effects
Addition information: Avoid release into the environment
Section 13 Disposal Considerations
13.1 Waste treatment methods
Regional legislation (waste): Disposal must be done according to official regulations.
Waste treatment methods: Dispose of this material and its container at hazardous or special waste collection point.
Sewage disposal recommendations: Not applicable as there is no release to wastewater.
Waste disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.
Section 14 Transport information
14.1 UN number
UN1263
14.2 UN proper shipping name
Paint-related materials including paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid filler, and liquid lacquer base, or paint related material including paint thinning, drying, removing, or reducing compound
14.3 Transport hazard class(es)
Class 3
Danger Label
14.4 Packing group
Not Applicable
14.5 Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6 Special precautions for user
Not applicable
Section 15 Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific of the substance or mixture
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.2 Chemical safety assessment
No chemical safety assessment has been carried out
Section 16 Other Information
No other information available